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Journal of the Electrochemical Society, Vol.154, No.9, G193-G197, 2007
Fabrication and electrical properties of strain-modulated epitaxial Ba0.5Sr0.5TiO3 thin-film capacitors
Ba0.5Sr0.5TiO3 (BST) epi layers 500 angstrom thick with different magnitudes of lattice distortion were fabricated by growing films on various perovskite oxide electrodes. The variations in the misfits between the BST and the bottom electrodes enable the strain manipulation of these BST epi layers. The 500 angstrom thick BST epi layer on the SrRuO3-coated SrTiO3 (STO) substrate is almost completely constrained by the SrRuO3 bottom electrode. The 500 angstrom thick BST epi layers are partially constrained on the Nb-doped STO, LaNiO3-coated STO, and La0.7Sr0.3MnO3-coated STO substrates. A suitable degree of lattice distortion of the BST epi layers is required to obtain a large dielectric constant; this fact is consistent with expectations based on the softening of the soft mode phonon. Variations to the electrical characteristics of the BST epi layers were considered with reference to changes in the degree of the lattice distortion of the BST epi layers. (c) 2007 The Electrochemical Society.