An alternative solution to the reduction of a discharge of residual nitric oxide and nitrogen dioxide into atmosphere has been proposed. Instead of using methane or ammonia for SCR or gas absorption into alkali solutions, which are the most popular treatment methods of tail gases, now the use of powerful oxidant-ozone capable of transforming nitrous acid and nitric oxides into nitrogen of the highest oxidation level-could be employed for this purpose. As the intensive oxidation and ozonation of nitrous acid is the heterogeneous gas-liquid process, the solubility of oxygen and ozone in HNO2/HNO3 aqueous solution was necessary to be determined. Variations of reaction rates depending on temperature, ozone dose and nitrous and nitric acid concentrations were studied experimentally. The kinetic model of the reactions, 2HNO(2) + O-2 -> 2HNO(3) and HNO2 + 03 -> 02 + HNO3, were proposed and the kinetic parameters (rate constants and activation energies) were estimated on the basis of experimental data in semi-batch laboratory gas-liquid contactor with the liquid phase drawn from an absorption column in the nitric acid plant. The determined kinetic parameters were then used in designing and modeling of the oxidation of nitrous acid using ozone-oxygen mixture in a continuous bubble column. The model consists of mass transfer kinetic equations and material balance equations for the gas and liquid phases. The co-current flow of gas and liquid phases and the complex kinetics of chemical reaction in the liquid phase were taken into account. The variation of the following process conditions, flow rate, compositions of the gas and liquid phases, temperature, and pressure in the bubble column of different diameters and heights, were studied in numerical solutions of the proposed model. (c) 2007 Elsevier Ltd. All rights reserved.