고온다습 조건이 탄소섬유/PEEK 복합재료의 계면전단강도에 미치는 영향 연구

강석민; 이명천

Polymer(Korea), Vol.19, No.3, 302-308, May, 1995

Export Citation

고온다습 조건이 탄소섬유/PEEK 복합재료의 계면전단강도에 미치는 영향 연구

Studies on the Effects of Hydrothermal Conditions on the Interfacial Shear Strength of Carbon Fiber/PEEK Composite

강석민, 이명천

초록

PEEK 수지가 인장변형될 때 일어나는 cold-drawing 현상을 이용한 single fiber fragment법으로 탄소섬유/PEEK 수지계의 계면전단강도를 성공적으로 측정하였다. 또한, 이 기법을 이용하여 고온다습 조건이 탄소섬유/PEEK 수지계의 계면전단강도에 미치는 영향을 조사하였다. 고온다습 조건을 주기 위해서는 45, 65 그리고 85℃의 증류수 속에 각각 3일, 7일 그리고 15일 동안 담그었다. 고온가습조건으로 처리된 시편들은 Instron을 이용하여 계면결합력을 측정하였다. 이 결과, 탄소섬유/PEEK 수지계의 계면전단강도는 45, 65 그리고 85℃의 증류수 속에 15일 동안 처리하였을때 각각 3.5, 11.6 그리고 15.6% 감소하였다.

Based on the cold-drawing phenomena of dogbone type PEEK specimen during the tensile deformation, single fiber fragment technique is applied successfully to measure the interfacial shear strength of carbon fiber/PEEK system. Also, this technique is used to investigate the hygrothermal effects on the interfacial shear strength of carbon fiber/PEEK system. To provide the hygrothermal condition, each sample is immersed in 45, 65 and 85℃ distilled water for 3, 7 and 15 days, respectively. The interfacial shear strength of the hygrothermally treated specimens is measured by Instron. The experimental results show that the interfacial shear strength of carbon fiber/PEEK system decreased 3.5, 11.6 and 15.6%, respectively, after 15 days immersion in 45, 65 and 85℃ distilled water.

Keywords:carbon fiber/PEEK;hygrothermal;interfacial shear strength

[References]

Hull D, "An Introduction to Composite Materials," Cambridge University Press, Cambridge, England (1981)
Drzal LT, Rich MJ, Lloyd PF, J. Adhes., 16, 1 (1983)
Scola DA, Brooks CS, J. Adhes., 2, 213 (1970)
Sawada Y, Shindo A, Nakanishi Y, Proc. 6th Int. Conf. on Composite Materials, 5, 448, Elsevier Applied SciencePublishers, Ltd., Barking, London (1987)
Ehrburger P, Herque JJ, Donnett JB, Proc. 5th Int. Conf. on Carbon and Graphite, London, 398-404 (1978)
Dorey G, Harvey J, "Interfaces in Polymer, Ceramic, and Metal Matrix Composites," H. Shida, ed., pp. 693-701, Elsevier Science Publishing Co., Inc., New York, NY (1988)
Kaelble DH, Dynes PJ, Crane LW, Maus L, J. Adhes., 7, 25 (1975)
Daukeys RJ, J. Adhes., 5, 211 (1973)
Herrick JW, Proc. 23rd Ann. Tech. Conf. SPI, 16A, 1-8 (1968)
Molleyre F, Bastick M, Proc. 4th London Intern. Conf. on Carbon and Graphite, Soc. Chem. Ind., London, 190-200 (1974)
Farra NR, Ashbee KHG, J. Phys. D: Appl. Phys., 111, 1009 (1978)
Dewimille B, Bunsell AR, Composites, Jan., 35 (1983)
Leung CL, Kaelble DH, ACS Symp. Ser. 132, C. May, ed., 419-434 (1980)
Sung YK, Gregonis DE, John MS, Andrade JD, J. Appl. Polym. Sci., 26, 3719 (1981)
Pipes RB, Vinson JR, Chou TW, J. Compos. Mater., 10, 129 (1976)
Browning CE, Polym. Eng. Sci., 18, 16 (1978)
Ashbee KHG, Sargent JP, Walter E, "The Role of Ploymeric Matrix in the Processing and Structural Properties of Composite Materials," J. Seferis and L. Nicolais, Eds., pp. 517-528, Plenum Press, New York (1983)
Jackson SP, Weitman Y, 5th Intern. Conf. on Comp. Matr. ICCM-V, 1435-1452 (1985)
Tsotsis TK, Weitsman Y, J. Compos. Mater., 24, 483 (1990)
Eakins WJ, ASTM STP 452, American Society for Testing and Materials, 137-148 (1969)
Farra NR, Ashbee KHG, J. Phys. D: Appl. Phys., 11, 1009 (1978)
Dewimille B, Bunsell AR, Composites, Jan., 35 (1983)
Kaelble DH, Dynes PJ, Cirlin EH, J. Adhes., 6, 23 (1974)
Kaelble DH, Dynes PJ, Crane LW, J. Adhes., 7, 25 (1974)
Miller B, Muri P, Rebenfeld L, Compos. Sci. Technol., 28, 17 (1987)
Penn LS, Lee SM, J. Compos. Tech. Res., 11, 23 (1989)
Greszczuk LB, ASTM STP 452, American Society for Testing and Mateirals, 42-58 (1969)
Piggott MR, Dai SR, "Interface in Polymer, Ceramic, and Metal Matrix Composites," Hatsuo Ishida, Editor, 481-488 (1988)
Piggott MR, Anderson D, Proceedings of the American Society for Composites, 5th Technical Conference, East Lansing, Michigan, 227-237 (1990)
Marshall P, Price J, Composites, 22, 53 (1991)
Wells JK, Beaumont PWR, J. Mater. Sci., 20, 1275 (1985)
Mandell JF, Chen JH, McGarry FJ, Int. J. Adhes. Adhes., 40 (1980)
Mandell JF, Grande DH, Tsiang TH, McGarry FJ, ASTM STP 893, J.M. Whitney, ed., pp. 87-108, American Society for Testing and Materials, Philadelphia (1986)
Caldwell DL, Cortez FM, Comp. Polym., 1, 138 (1988)
Narkis M, Chen JH, Pipes RB, Polym. Compos., 9, 245 (1988)
Kelly A, Tyson WR, J. Mech. Phys. Solids, 13, 329 (1965)
Drzal LT, Rich MJ, Camping JD, Park WJ, Proc. of 1980 Conf. of RP/Composites Inst., Paper 20-C, 1-7 (1980)
Drzal LT, Rich MJ, Lloyd PF, J. Adhes., 16, 1 (1983)
Rao V, Drzal LT, Polym. Compos., 12, 48 (1991)
Sohn DW, Sung N, Polym. Mater. Sci. Eng. Proceed., 62, 43 (1990)

[Referenced By]

[1] Hull D, "An Introduction to Composite Materials," Cambridge University Press, Cambridge, England (1981)

[2] Drzal LT, Rich MJ, Lloyd PF, J. Adhes., 16, 1 (1983)

[3] Scola DA, Brooks CS, J. Adhes., 2, 213 (1970)

[4] Sawada Y, Shindo A, Nakanishi Y, Proc. 6th Int. Conf. on Composite Materials, 5, 448, Elsevier Applied SciencePublishers, Ltd., Barking, London (1987)

[5] Ehrburger P, Herque JJ, Donnett JB, Proc. 5th Int. Conf. on Carbon and Graphite, London, 398-404 (1978)

[6] Dorey G, Harvey J, "Interfaces in Polymer, Ceramic, and Metal Matrix Composites," H. Shida, ed., pp. 693-701, Elsevier Science Publishing Co., Inc., New York, NY (1988)

[7] Kaelble DH, Dynes PJ, Crane LW, Maus L, J. Adhes., 7, 25 (1975)

[8] Daukeys RJ, J. Adhes., 5, 211 (1973)

[9] Herrick JW, Proc. 23rd Ann. Tech. Conf. SPI, 16A, 1-8 (1968)

[10] Molleyre F, Bastick M, Proc. 4th London Intern. Conf. on Carbon and Graphite, Soc. Chem. Ind., London, 190-200 (1974)

[11] Farra NR, Ashbee KHG, J. Phys. D: Appl. Phys., 111, 1009 (1978)

[12] Dewimille B, Bunsell AR, Composites, Jan., 35 (1983)

[13] Leung CL, Kaelble DH, ACS Symp. Ser. 132, C. May, ed., 419-434 (1980)

[14] Sung YK, Gregonis DE, John MS, Andrade JD, J. Appl. Polym. Sci., 26, 3719 (1981)

[15] Pipes RB, Vinson JR, Chou TW, J. Compos. Mater., 10, 129 (1976)

[16] Browning CE, Polym. Eng. Sci., 18, 16 (1978)

[17] Ashbee KHG, Sargent JP, Walter E, "The Role of Ploymeric Matrix in the Processing and Structural Properties of Composite Materials," J. Seferis and L. Nicolais, Eds., pp. 517-528, Plenum Press, New York (1983)

[18] Jackson SP, Weitman Y, 5th Intern. Conf. on Comp. Matr. ICCM-V, 1435-1452 (1985)

[19] Tsotsis TK, Weitsman Y, J. Compos. Mater., 24, 483 (1990)

[20] Eakins WJ, ASTM STP 452, American Society for Testing and Materials, 137-148 (1969)

[21] Farra NR, Ashbee KHG, J. Phys. D: Appl. Phys., 11, 1009 (1978)

[22] Dewimille B, Bunsell AR, Composites, Jan., 35 (1983)

[23] Kaelble DH, Dynes PJ, Cirlin EH, J. Adhes., 6, 23 (1974)

[24] Kaelble DH, Dynes PJ, Crane LW, J. Adhes., 7, 25 (1974)

[25] Miller B, Muri P, Rebenfeld L, Compos. Sci. Technol., 28, 17 (1987)

[26] Penn LS, Lee SM, J. Compos. Tech. Res., 11, 23 (1989)

[27] Greszczuk LB, ASTM STP 452, American Society for Testing and Mateirals, 42-58 (1969)

[28] Piggott MR, Dai SR, "Interface in Polymer, Ceramic, and Metal Matrix Composites," Hatsuo Ishida, Editor, 481-488 (1988)

[29] Piggott MR, Anderson D, Proceedings of the American Society for Composites, 5th Technical Conference, East Lansing, Michigan, 227-237 (1990)

[30] Marshall P, Price J, Composites, 22, 53 (1991)

[31] Wells JK, Beaumont PWR, J. Mater. Sci., 20, 1275 (1985)

[32] Mandell JF, Chen JH, McGarry FJ, Int. J. Adhes. Adhes., 40 (1980)

[33] Mandell JF, Grande DH, Tsiang TH, McGarry FJ, ASTM STP 893, J.M. Whitney, ed., pp. 87-108, American Society for Testing and Materials, Philadelphia (1986)

[34] Caldwell DL, Cortez FM, Comp. Polym., 1, 138 (1988)

[35] Narkis M, Chen JH, Pipes RB, Polym. Compos., 9, 245 (1988)

[36] Kelly A, Tyson WR, J. Mech. Phys. Solids, 13, 329 (1965)

[37] Drzal LT, Rich MJ, Camping JD, Park WJ, Proc. of 1980 Conf. of RP/Composites Inst., Paper 20-C, 1-7 (1980)

[38] Drzal LT, Rich MJ, Lloyd PF, J. Adhes., 16, 1 (1983)

[39] Rao V, Drzal LT, Polym. Compos., 12, 48 (1991)

[40] Sohn DW, Sung N, Polym. Mater. Sci. Eng. Proceed., 62, 43 (1990)