Potential and current density distributions were modelled and measured for an electrochemical cell with a bipolar electrode. The dimension of the bipolar electrode in the direction of current flow was extended, to enable experimental determination of the electrode potential and the local current densities at various positions inside the electrolyte and in the electrode body. The experimental results showed that the most active regions of the bipolar electrode are located at the ends of the bipolar electrode facing the terminal electrodes. The equations corresponding to the mathematical model of the experimental cell were solved using the finite volume method and gave very good qualitative agreement with the experimental data. However, some discrepancies between model predictions and experimental data were evident in the active parts of the bipolar electrode and in the variation of the terminal voltage with the total current. This was explained in terms of the active electrolyte cross-section and the electrode surface area being diminished due to the presence of gas bubbles in the system.