Industrial & Engineering Chemistry Research, Vol.46, No.20, 6449-6455, 2007
Platinum catalyst on multiwalled carbon nanotubes for the catalytic wet air oxidation of phenol
Bare oxidized carbon nanotubes (CNTs) and carboxylated CNTs treated with sodium carbonate to generate carboxylate groups on the outer surface were used to prepare platinum catalysts by two different methods: incipient wetness and excess solution impregnation. The catalysts were characterized by N-2 adsorption (BET), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and X-ray fluorescence (XRF). These catalysts were tested in catalytic wet air oxidation of phenol aqueous solutions in a continuous trickle-bed reactor at 2.0 MPa of total pressure and temperatures of 160 and 200 degrees C. The phenol and TOC conversions obtained at steady state were above 94% and 80%, respectively, and the activity per catalyst weight was 30.0 mmol(phenol)center dot gcat(-1)center dot h(-1) in steady-state conditions. This means the first use of CNT in catalytic wet air oxidation of phenol was in continuous trickle-bed reactors (CTBR).