The component and structure Of CO2 corrosion scale formed on N80 tubing steel were studied by using X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscopy (SEM); the electrochemical property of N80 steel covered by corrosion scale was investigated by electrochemical impedance spectroscopy (EIS). The results shows a double-layer structure of the corrosion scale, in which the principal component of the outer layer is FeCO3 with a limited amount of partial derivative-FeOOH; while for the inner scale, FeCO3 is still the major component, but some Fe positions in FeCO3 lattice are substituted by Ca, and form a composite compound of (Fe,Ca)CO3 in the inner scale. EIS study shows that the anodic impedance spectrum has three time constants, i.e., the capacitance at high frequency, Warburg impedance at middle frequency and capacitance at low frequency. (c) 2007 Elsevier B. V. All rights reserved.