In this study, performances of two pure hydrocarbons and seven mixtures composed of propylene, propane, HFC152a, and dimethylether were measured to substitute for HCFC22 in residential air-conditioners and heat pumps. Thermodynamic cycle analysis was carried out to determine the optimum compositions before testing and actual tests were performed in a breadboard-type laboratory heat pump/air-conditioner at the evaporation and condensation temperatures of 7 and 45 degrees C, respectively. Test results show that the coefficient of performance of these mixtures is up to 5.7% higher than that of HCFC22. While propane showed a 11.5% reduction in capacity, most of the fluids had a similar capacity to that of HCFC22. For these fluids, compressor-discharge temperatures were reduced by 11-17 degrees C. For all fluids tested, the amount of charge was reduced by up to 55% as compared to HCFC22. Overall, these fluids provide good performances with reasonable energy-savings without any environmental problem and thus can be used as long-term alternatives for residential air-conditioning and heat-pumping applications. (c) 2007 Elsevier Ltd. All rights reserved.