Journal of Chemical Thermodynamics, Vol.39, No.9, 1292-1299, 2007
Partial molar volumes of organic solutes in water. XVIII: Selected polyethers(aq) and 3,6-dioxa-1-heptanol(aq) at T = (298 to 573) K and at pressures up to 30 MPa
Density data for dilute aqueous solutions of four aliphatic ethers (2,5-dioxahexane, 3,5-dioxaheptane, 3,6-dioxaoctane, and 2,5,8-trioxanonane) and one ether-alcohol (3,6-dioxa-1-heptanol) are presented together with partial molar volumes at infinite dilution calculated from the experimental data. The measurements were performed at temperatures from T = 298 K up to either T = 443 K (3,5-dioxaheptane) or T = 573 K (other solutes) and at pressures close to the saturated vapour pressure of water, at pressures between 15 and 20 MPa and at p = 30 MPa. The data were obtained using a high-temperature high-pressure flow vibrating-tube densimeter. (c) 2007 Elsevier Ltd. All rights reserved.
Keywords:density;partial molar volume;aqueous ethers;2,5-dioxahexane;3,5-dioxaheptane;3,6-dioxaoctane;2,5,8-trioxanonane;3,6-dioxa-1-heptanol;high temperature;high pressure