Journal of Applied Polymer Science, Vol.106, No.1, 130-137, 2007
Influence of different Amides as plasticizer on the properties of soy protein plastics
A series of amide-plasticized soy protein isolate materials were prepared by hot compression-molding techniques at 140 degrees C and 20 MPa. The plasticizing efficiency of amides was in the order of formamide > acetamide > acrylamide resulting from scanning electron microscopy, optical transmittance and differential scanning calorimetry. The results from torque rheology indicated that flowability and processability could be improved by adding amide as plasticizers. All of the sheets showed single glass transition temperature obtained by differential scanning calorimetry, indicating good compatibility between amide and soy protein. The water uptake of the plastics sheets and effects of moisture content on the thermal and mechanical properties were also investigated. The glass transition temperature and tensile strength decreased with an increase of moisture content in sheets. Formamide was considered as the best plasticizer of three amides because of the higher plasticizing efficiency and water resistance of SFm sheets. (c) 2007 Wiley Periodicals, Inc.