Journal of Crystal Growth, Vol.309, No.1, 93-96, 2007
The preferential orientation of the directionally solidified Si-TaSi2 eutectic in situ composite
The Si-TaSi2 eutectic in situ composite is a favorable field emission material due to relatively low work function, good electron conductivity, and three-dimensional array of Schottky junctions grown in the composite spontaneously. The preferential orientation during directional solidification is determined by the growth anisotropy. In order to obtain the preferential direction of the steady-state crystal growth, the transmission electron microscopy (TEM) is used for analysis. It is found that the preferential orientation of the SiTaSi2 eutectic in situ composite prepared by Czochralski (CZ) technique is [3 (3) over bar(2) over bar] Si parallel to[0001] TaSi2, (220)Si parallel to(2 (2) over bar 00) TaSi2. Whereas the preferential orientation of the Si-TaSi2 eutectic in situ composite prepared by electron beam floating zone melting (EBFZM) technique is [0 (1) over bar(1) over bar] Si parallel to[0001] TaSi2,(0 (1) over bar1) Sill(0 (1) over bar 11)TaSi2. The preferential directions of the Si-TaSi2 eutectic in situ composites prepared by two kinds of crystal growth techniques are distinctly different from each other, which results from different solid-liquid interface temperatures on account of the different crystal growth conditions, e.g. different solidification rate, different temperature gradient, different solid-liquid interface curvature and different kinetic undercooling. (C) 2007 Elsevier B.V. All rights reserved.
Keywords:directional solidification;eutectic in situ composite;transmission electron microscopy;Czochralski method;electron beam floating zone melting;Si-TaSi2