Journal of the American Ceramic Society, Vol.90, No.12, 4050-4054, 2007
Low-temperature oxidation embrittlement of SiC (Nicalon((TM)))/CAS ceramic matrix composites
The influence of extended duration (up to 1000 h), low temperature oxidation heat-treatments (375 degrees-600 degrees C) has been assessed using a model ceramic matrix composite system with a graphitic fiber/matrix interphase. For this study a Nicalon((TM)) fiber reinforced CaO-Al2O3-SiO2 matrix composite was selected (Nicalon((TM))/CAS), which possesses a thin (similar to 20-40 nm) carbon-based interphase. Oxidation exposure has been conducted under both unloaded and static fatigue-loaded conditions. For unstressed oxidation exposure, degradation of the carbon-based interphase is apparent at temperatures as low as 375 degrees C, after 1000 h exposure, resulting in a transition to a nominally brittle failure mode (i.e., negligible fiber pull-out). The degree of mechanical property degradation increases with increasing temperature, such that strength degradation, and a transition to nominally brittle failure, is apparent after just 10 h at 600 degrees C. Static fatigue loading between 450 degrees and 600 degrees C demonstrated generally similar trends, with reduced lifetimes being observed with increasing temperature. Based upon the unloaded oxidation experiments, combined with previously obtained intermediate and high-temperature oxidation stability studies, a simple environmental embrittlement failure mechanism map is presented for Nicalon((TM))/CAS. The implications of this study for advanced composite designs with multiple thin carbon-based interphase layers are also discussed.