Journal of Supercritical Fluids, Vol.20, No.3, 221-228, 2001
Bubble-point pressures of the binary system carbon dioxide plus linalool
A synthetic method was used to investigate high-pressure vapor-liquid equilibria of the binary system carbon dioxide + linalool. The bubble points of this system were measured at carbon dioxide mole fractions from 0.2 up to 0.993 and within temperature and pressure ranges of 283-371 K and 1.4-14.7 MPa, respectively. Critical points of this binary system were also determined experimentally for a carbon dioxide mole fraction range from 0.93 up to 0.993. The results were correlated by the Stryjek-Vera modified version of the Peng-Robinson equation of state using one-fluid van der Waals mixing rules with both one and two interaction parameters. (C) 2001 Elsevier Science B.V. All rights reserved.
Keywords:vapor-liquid equilibrium;bubble points;critical points;CO2;linalool;citrus peel oil;orange oil;Peng-Robinson-Stryjek-Vera (PRSV) equation of state