Synthesis and Thermal Study on Viscose Rayon Succinate Coupled with Metals and Viscose Rayon Succinic Silane

Aruukhan Dashkhuu Khasbaatar; Yong Jin Chun; Ung Su Choi

Journal of Industrial and Engineering Chemistry, Vol.13, No.7, 1109-1116, December, 2007

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Synthesis and Thermal Study on Viscose Rayon Succinate Coupled with Metals and Viscose Rayon Succinic Silane

Aruukhan Dashkhuu Khasbaatar, Yong Jin Chun¹, and Ung Su Choi^†

Energy Mechanics Research Center, Korea Institute of Science and Technology, Seoul 130-650, Korea
¹Department of New Matr. & Appl. Chemistry, Chung Woon University, Hingsung-gun 350-701, Korea

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In this article, synthesis of viscose rayon succinate (VRS), viscose rayon succinic silanate (VRSS) and viscose rayon succinate with metal complexes were confirmed by 13C solid state nuclear magnetic resonance (NMR) spectroscopy and Fourier transform infrared (FT-IR) spectroscopy. Thermal properties of the synthesized materials were studied with thermogravimetric analysis (TGA) and limited oxygen index (LOI) testing. VRS was less stable than viscose rayon (VR) at high temperatures. However, weight residues of metal complexed VRS increased in comparison to VR and VRS after char formation at high temperatures. The amount of weight residue could be described in the following order: VRS-Cu > VRS-Cr > VRS-Al > VRS-Ni > VR > VRS. All of the materials were found to be effective as flame retardants.

Keywords:viscose rayon;succination;silanation;metal complex;TGA

[References]

Gross RA, Kalan B, Science, 297, 803 (2002)
El Seoud OA, Heinze T, Adv. Polym. Sci., 186, 103 (2005)
Edgar KJ, Buchanan CM, Debenham JS, Rundquist PA, Seiler BD, Shelton MC, Tindall D, Prog. Polym. Sci, 26, 1605 (2001)
Sairam M, Sreedhar B, Mohan Rao DV, Palaniappan S, Polym. Adv. Technol., 14, 477 (2003)
Luo J, Sun Y, J. Appl. Polym. Sci., 100(4), 3288 (2006)
Huang MR, Li XG, J. Appl. Polym. Sci., 68(2), 293 (1998)
Jandura P, Riedl B, Kokta BV, Polym. Degrad. Stabil., 70, 387 (2000)
Gaibler DW, Rochefort WE, Wilson JB, Kelley SS, Cellulose, 11, 225 (2004)
Nada AAMA, Hassan ML, J. Appl. Polym. Sci., 102(2), 1399 (2006)
Pan CK, Liu F, Sutton P, Vivilecchia R, Thermochim. Acta, 435(1), 11 (2005)
Kandola BK, Horrocks AR, Price D, Coleman GV, J. Macromol. Sci.-Rev. Macromol. Chem. Phys., C36, 721 (1996)
Lu SY, Hamerton I, Prog. Polym. Sci, 27, 1661 (2002)
Lavine MS, Science, 306, 375 (2004)
Grand AF, Wlikie CA, Fire Retardancy of Polymeric Materials, ed, Marcel Dekker Inc, New York (2000)
Ko YG, Choi US, Ahn BG, Ahn DJ, J. Polym. Sci. A: Polym. Chem., 38(15), 2815 (2000)
Qu H, Wu W, Jiao Y, Xu J, Polym. Int., 54, 1469 (2005)
Hanna AA, Basta AH, Ek-Saied H, Abadir IF, Die Angew. Makromol. Chem., 260, 1 (1998)
Khasbaatar AD, Ko YG, Choi US, React. Funct. Polym., 67, 312 (2007)
Peydecastaing J, Girardeau S, Vaca-Garcia C, Borredon ME, Cellulose, 13, 95 (2005)
Mitsunobu O, Wada M, Sano T, J. Am. Chem. Soc., 94, 679 (1972)
Colthup NB, Daly LH, Wiberley SE, Introduction to Infrared and Raman Spectroscopy, Academic press inc, London (1964)
Barsbay M, Can HK, Guner A, Rzaev ZMO, Polym. Adv. Technol., 16, 32 (2005)
Nehls I, Wagenhnecht W, Philipp B, Stscherbina D, Prog. Polym. Sci, 19, 29 (1994)
El Nahhal IM, Chehimi MM, Cordier C, Dodin G, J. Non-Cryst. Solids, 275, 142 (2000)
Emsley AM, Stevens GC, Cellulose, 1, 26 (1994)
Nelson MI, Combust. Theory Model., 5, 59 (2001)
Song YW, Lee JB, Park CS, Hwang GJ, Choi SI, Yang HS, Kim YH, J. Ind. Eng. Chem., 12(2), 255 (2006)
Park SJ, Li K, Jin FL, J. Ind. Eng. Chem., 11(5), 720 (2005)

[Referenced By]

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[1] Gross RA, Kalan B, Science, 297, 803 (2002)

[2] El Seoud OA, Heinze T, Adv. Polym. Sci., 186, 103 (2005)

[3] Edgar KJ, Buchanan CM, Debenham JS, Rundquist PA, Seiler BD, Shelton MC, Tindall D, Prog. Polym. Sci, 26, 1605 (2001)

[4] Sairam M, Sreedhar B, Mohan Rao DV, Palaniappan S, Polym. Adv. Technol., 14, 477 (2003)

[5] Luo J, Sun Y, J. Appl. Polym. Sci., 100(4), 3288 (2006)

[6] Huang MR, Li XG, J. Appl. Polym. Sci., 68(2), 293 (1998)

[7] Jandura P, Riedl B, Kokta BV, Polym. Degrad. Stabil., 70, 387 (2000)

[8] Gaibler DW, Rochefort WE, Wilson JB, Kelley SS, Cellulose, 11, 225 (2004)

[9] Nada AAMA, Hassan ML, J. Appl. Polym. Sci., 102(2), 1399 (2006)

[10] Pan CK, Liu F, Sutton P, Vivilecchia R, Thermochim. Acta, 435(1), 11 (2005)

[11] Kandola BK, Horrocks AR, Price D, Coleman GV, J. Macromol. Sci.-Rev. Macromol. Chem. Phys., C36, 721 (1996)

[12] Lu SY, Hamerton I, Prog. Polym. Sci, 27, 1661 (2002)

[13] Lavine MS, Science, 306, 375 (2004)

[14] Grand AF, Wlikie CA, Fire Retardancy of Polymeric Materials, ed, Marcel Dekker Inc, New York (2000)

[15] Ko YG, Choi US, Ahn BG, Ahn DJ, J. Polym. Sci. A: Polym. Chem., 38(15), 2815 (2000)

[16] Qu H, Wu W, Jiao Y, Xu J, Polym. Int., 54, 1469 (2005)

[17] Hanna AA, Basta AH, Ek-Saied H, Abadir IF, Die Angew. Makromol. Chem., 260, 1 (1998)

[18] Khasbaatar AD, Ko YG, Choi US, React. Funct. Polym., 67, 312 (2007)

[19] Peydecastaing J, Girardeau S, Vaca-Garcia C, Borredon ME, Cellulose, 13, 95 (2005)

[20] Mitsunobu O, Wada M, Sano T, J. Am. Chem. Soc., 94, 679 (1972)

[21] Colthup NB, Daly LH, Wiberley SE, Introduction to Infrared and Raman Spectroscopy, Academic press inc, London (1964)

[22] Barsbay M, Can HK, Guner A, Rzaev ZMO, Polym. Adv. Technol., 16, 32 (2005)

[23] Nehls I, Wagenhnecht W, Philipp B, Stscherbina D, Prog. Polym. Sci, 19, 29 (1994)

[24] El Nahhal IM, Chehimi MM, Cordier C, Dodin G, J. Non-Cryst. Solids, 275, 142 (2000)

[25] Emsley AM, Stevens GC, Cellulose, 1, 26 (1994)

[26] Nelson MI, Combust. Theory Model., 5, 59 (2001)

[27] Song YW, Lee JB, Park CS, Hwang GJ, Choi SI, Yang HS, Kim YH, J. Ind. Eng. Chem., 12(2), 255 (2006)

[28] Park SJ, Li K, Jin FL, J. Ind. Eng. Chem., 11(5), 720 (2005)