화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.24, No.6, 1022-1026, November, 2007
Preparation of Ag-sensitized ZnO and its photocatalytic performance under simulated solar light
E-mail:
ZnO was prepared rapidly by microwave heating method. The results of scanning electron microscopy show that the leaflike ZnO is composed of self-assembled ZnO particles of 30-50 nm. Ag-sensitized ZnO composite was prepared by UV-photoreduction and glycol reduction, respectively. The composite was characterized by means of scanning electron microscopy, X-ray diffraction and photoluminescence. The ZnO and Ag/ZnO prepared were applied in photocatalytic degradation of phenol and methyl orange as model of organic pollutant in water under simulated solar light. The results show that Ag doping in both methods of UV-photoreduction and glycol reduction can remarkably improve the photocatalytic activity of ZnO under simulated solar light. The utilization ratio of Ag in glycol reduction is high and the optimum content of Ag in Ag/ZnO composite is only 1.33%. Therefore, the glycol reduction is a novel and excellent method for preparing Ag-sensitized ZnO composite with high photocatalytic activity.
  1. Fujishima A, Honda K, Nature, 238, 37 (1972)
  2. Du PW, Schneider J, Jarosz P, Eisenberg R, J. Am. Chem. Soc., 128(24), 7726 (2006)
  3. Maeda K, Teramura K, Lu DL, Takata T, Saito N, Inoue Y, Domen K, Nature, 440, 295 (2006)
  4. Guillard C, Debayle D, Gagnaire A, Jaffrezic H, Herrmann JM, Mater. Res. Bull., 39, 1445 (2004)
  5. Yeber MC, Rodriguez J, Freer J, Duran N, Mansilla HD, Chemosphere, 41, 1193 (2000)
  6. Dindar B, Icli S, J. Photochem. Photobiol. A-Chem., 140, 263 (2001)
  7. Lee J, Nam SC, Tak Y, Korean J. Chem. Eng., 22(1), 161 (2005)
  8. Luo H, Takata T, Lee Y, Zhao J, Domen K, Yan Y, Chem. Mater., 16, 846 (2004)
  9. Skanadan G, Chen YJ, Glumac N, Kear BH, Nanostruct. Mater., 11, 149 (1999)
  10. Shinagawa T, Izaki M, Inui H, Murase K, Awakura Y, J. Electrochem. Soc., 152, 736 (2005)
  11. Masumoto Y, J. Solid State Chem., 126, 227 (1996)
  12. Anpo M, Catal. Surv. Jpn., 1, 169 (1997)
  13. Li D, Haneda H, J. Photochem. Photobiol. A-Chem., 155, 171 (2003)
  14. Asahi R, Morikawa T, Ohwaki T, Aoki K, Taga Y, Science, 296, 269 (2001)
  15. Irie H, Watanabe Y, Hashimoto K, J. Phys. Chem. B, 107(23), 5483 (2003)
  16. Li D, Haneda H, Ohashi N, Hishita S, Yoshikawa Y, Catal. Today, 93-95, 895 (2004)
  17. Bedja I, Kamat PV, Hua X, Lappin AG, Hotchandani S, Langmuir, 13(8), 2398 (1997)
  18. Bahadur L, Srivastava P, Sol. Energy Mater. Sol. Cells, 79, 235 (2003)
  19. Bessekhouad Y, Robert D, Weber JV, Catal. Today, 101(3-4), 315 (2005)
  20. Bessekhouad Y, Robert D, Weber JV, J. Photochem. Photobiol. A-Chem., 163, 569 (2004)
  21. Abushama JAM, Johnston S, Moriarty T, Teeter G, Ramanathan K, Noufi R, Prog. Photovoltaics, 12, 39 (2004)
  22. Height MJ, Pratsinis SE, Mekasuwandumrong O, Praserthdam P, Appl. Catal. B: Environ., 63(3-4), 305 (2006)
  23. Wang RH, Xin JHZ, Yang Y, Liu HF, Xu LM, Hu JH, Appl. Surf. Sci., 227(1-4), 312 (2004)
  24. Angadi B, Jung YS, Choi WK, Kumar R, Jeong K, Shin SW, Lee JH, Song JH, Khan MW, Srivastava JP, Appl. Phys. Lett., 88, 142502 (2006)
  25. Sahu DR, Huang JL, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 130, 295 (2006)
  26. Yamamoto Y, Hayashi Y, Tachibana Y, Shimodaira N, Kudo M, Appl. Surf. Sci., 203, 863 (2003)
  27. Zhao SQ, Zhou YL, Zhao K, Liu Z, Han P, Wang SF, Xiang WF, Chen ZH, Lu HB, Cheng BL, Yang GZ, Physica B, 373, 154 (2006)
  28. Kawano K, Komatsu M, Yajima Y, Haneda H, Maki H, Yamamoto T, Appl. Surf. Sci., 189(3-4), 265 (2002)
  29. Stroyuk AL, Shvalagin VV, Kuchmii SY, J. Photochem. Photobiol. A-Chem., 173, 185 (2005)
  30. Jing LQ, Wang DJ, Wang BQ, Li SD, Xin BF, Fu HG, Sun JZ, J. Mol. Catal. A-Chem., 244(1-2), 193 (2006)
  31. Dai L, Chen XL, Wang WJ, Zhou T, Hu BQ, J. Phys. Condens. Matter, 15, 2221 (2003)
  32. Umar A, Ra HW, Jeong JP, Suh EK, Hahn YB, Korean J. Chem. Eng., 23(3), 499 (2006)
  33. Mahamuni S, Borgohain K, Bendre BS, Leppert VJ, Risbud SH, J. Appl. Phys., 85, 2861 (1999)
  34. Liu JP, Huang XT, Li YY, Zhong Q, Ren L, Mater. Lett., 60, 1354 (2006)
  35. Jing LQ, Qu YC, Wang BQ, Li SD, Jiang BJ, Yang LB, Fu W, Fu HG, Solar JZ, Sol. Energy Mater. Sol. Cells, 90, 1773 (2006)