Advanced Functional Materials, Vol.15, No.10, 1656-1664, 2005
Morphology of polymer/liquid-crystal nanotubes: Influence of confinement
Polymer/liquid-crystal (LC) tubes consisting of an approximately 30 nm thick poly(methyl methacrylate) (PMMA) layer on the outside and a 5 to 10 nm thick discotic liquid-crystal line layer on the inside of the tube walls have been prepared by wetting ordered porous alumina templates with a pore diameter of 400 nm. Decreasing the pore diameter to 60 nm results in a confinement-induced transition from a wetting state to a non-wetting state, and solid rods with a sequential morphology are obtained. The texture of the mesophase depends on the morphology type and the thermal history. Under certain conditions the LC mesophase exhibits a dominant, well-ordered planar texture where the discotic columns are aligned with the long axes of the tubes. The controlled generation of one-dimensional nano-objects possessing mesoscopic fine structures and intrinsic anisotropy should be the first step towards a rational design of miniaturized building blocks.