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Electrochemical and Solid State Letters, Vol.5, No.3, A51-A54, 2002
Current oscillations during CO electro-oxidation on smooth platinum
In this paper it is shown, for the first time, the presence of current oscillations in the electro-oxidation of carbon monoxide on a rotating platinum electrode. The current oscillations occur in a very restricted potential region around 950 mV vs. reversible hydrogen electrode, and may be observed for over 12 h. They are discussed in terms of the mechanism for CO electro-oxidation and the mutual influence of the processes of CO adsorption and formation of oxygenated species on the surface. (C) 2002 The Electrochemical Society.