A class of ambient temperature solid electrolyte based on an ＇inorganic salt-organic salt＇ hybrid system is reported. The hybrid system was investigated by the measurement of ionic conductivities and the interaction between the ions of the hybrid system was studied by Raman spectroscopy. The organic salt in the hybrid system not only promoted the dissociation of the lithium salt, but also provided the hybrid system with an improved rubbery property.