폴리아릴레이트-폴리스티렌 블록 공중합체와 폴리아릴레이트 혹은 폴리스티렌과의 상용성

안태완; 김정호; 정한모; 박이순; 박종윤

Polymer(Korea), Vol.16, No.1, 22-28, January, 1992

Export Citation

폴리아릴레이트-폴리스티렌 블록 공중합체와 폴리아릴레이트 혹은 폴리스티렌과의 상용성

Miscibility of Polyarylate-Polystyrene Block Copolymer with Polyarylate or Polystyrene

안태완, 김정호, 정한모, 박이순, 박종윤

초록

구성 블록의 분자량이 다양한 multiblock 구조의 폴리아릴레이트-폴리스티렌 블록 공중합체와 폴리아릴레이트 흑은 폴리스티렌과의 이원글렌드의 상용성을 조사하였다. 블록 공중합체 중의 동종 구조 블록의 분자량이 클수록, 이종 구조 블록의 분자량이 작을수록 해당 고분자와의 상용성이 증가함을 유리전이온도. 유리전이온도에서의 열용량의 변화로부터 관찰할 수 있었다.

Miscibility of binary blends of polyarylate-polystyrene multiblock copolymers of various block lengths with polyarylate or polystyrene was studied by thermal properties, i.e., glass transition temperature and heat capacity change at glass transition temperature. The miscibility of block copolymers with homopolymer, i.e., polyarylate or polystyrene, was increased as the length of the block with the same structure was increased and the length of the block with different structure was decreased.

[References]

Kressler J, Karasz FE, Kammer HW, Morgenstern U, Makromol. Chem., 191, 1623 (1990)
Xie H, Liu Y, Jiang M, Yu T, Makromol. Chem. Rapid Commun., 10, 115 (1989)
Whitmore MD, Noolandi J, Macromolecules, 18, 2486 (1985)
Rigby D, Roe RJ, Macromolecules, 17, 1778 (1984)
Kressler J, Kammer HW, Morgenstern U, Litauszki B, Berger W, Karasz FE, Makromol. Chem., 191, 243 (1990)
Han CD, Kim J, Kim JK, Chu SG, Macromolecules, 22, 3443 (1989)
Tucker PS, Barlow JW, Paul DR, Macromolecules, 21, 1678 (1988)
Tucker PS, Barlow Jw, Paul DR, J. Appl. Polym. Sci., 34, 1817 (1987)
Ahn TO, Youn YJ, Jeong HM, Polym.(Korea), 14(1), 14 (1990)
Ahn TO, Youn YJ, Jeong HM, Polym.(Korea), 13(7), 581 (1989)
Kallitsis JK, Sotiropoulou DD, Kalfoglou NK, Polymer, 29, 1233 (1988)
Ahn TO, Kim JH, Jeong HM, Lee SW, Park JY, Polym.(Korea), 14(4), 417 (1990)
Ahn TO, Kim JH, Lee JC, Jeong HM, Park JY, J. Polym. Sci. A: Polym. Chem., to submitted
Inoue H, Matsumoto A, Matsukawa K, Ueda A, Nagai S, J. Appl. Polym. Sci., 41, 1815 (1990)
Walz R, Heitz W, J. Polym. Sci. A: Polym. Chem., 16, 1807 (1978)
Kim WN, Burns CM, J. Appl. Polym. Sci., 41, 1575 (1990)
Gaur U, Wunderlich B, Macromolecules, 13, 1618 (1980)
Ahn TO, Jeong HM, Lee SM, Lee YJ, Polym.(Korea), 13(4), 309 (1989)
Beckman EJ, Karasz FE, Porter RS, MacKnight WJ, VanHunsel J, Koningsveld R, Macromolecules, 21, 1193 (1988)

[Referenced By]

[1] Kressler J, Karasz FE, Kammer HW, Morgenstern U, Makromol. Chem., 191, 1623 (1990)

[2] Xie H, Liu Y, Jiang M, Yu T, Makromol. Chem. Rapid Commun., 10, 115 (1989)

[3] Whitmore MD, Noolandi J, Macromolecules, 18, 2486 (1985)

[4] Rigby D, Roe RJ, Macromolecules, 17, 1778 (1984)

[5] Kressler J, Kammer HW, Morgenstern U, Litauszki B, Berger W, Karasz FE, Makromol. Chem., 191, 243 (1990)

[6] Han CD, Kim J, Kim JK, Chu SG, Macromolecules, 22, 3443 (1989)

[7] Tucker PS, Barlow JW, Paul DR, Macromolecules, 21, 1678 (1988)

[8] Tucker PS, Barlow Jw, Paul DR, J. Appl. Polym. Sci., 34, 1817 (1987)

[9] Ahn TO, Youn YJ, Jeong HM, Polym.(Korea), 14(1), 14 (1990)

[10] Ahn TO, Youn YJ, Jeong HM, Polym.(Korea), 13(7), 581 (1989)

[11] Kallitsis JK, Sotiropoulou DD, Kalfoglou NK, Polymer, 29, 1233 (1988)

[12] Ahn TO, Kim JH, Jeong HM, Lee SW, Park JY, Polym.(Korea), 14(4), 417 (1990)

[13] Ahn TO, Kim JH, Lee JC, Jeong HM, Park JY, J. Polym. Sci. A: Polym. Chem., to submitted

[14] Inoue H, Matsumoto A, Matsukawa K, Ueda A, Nagai S, J. Appl. Polym. Sci., 41, 1815 (1990)

[15] Walz R, Heitz W, J. Polym. Sci. A: Polym. Chem., 16, 1807 (1978)

[16] Kim WN, Burns CM, J. Appl. Polym. Sci., 41, 1575 (1990)

[17] Gaur U, Wunderlich B, Macromolecules, 13, 1618 (1980)

[18] Ahn TO, Jeong HM, Lee SM, Lee YJ, Polym.(Korea), 13(4), 309 (1989)

[19] Beckman EJ, Karasz FE, Porter RS, MacKnight WJ, VanHunsel J, Koningsveld R, Macromolecules, 21, 1193 (1988)