The properties of imidazole (pyrazole) as a solvent for acidic protons in polymers and liquids are reported. The creation of protonic defects and the mobility of protons in these environments are found to be similar to the situation in corresponding water containing systems. The temperature stability is, however, increased and imidazole (pyrazole) is a stronger Bronstedt base compared to water, which may be useful for the application of such materials as electrochemical cells such as fuel cells and secondary batteries.