Electrochimica Acta, Vol.43, No.10-11, 1253-1256, 1998
A novel type of magnesium ion conducting polymer electrolyte
Polymer electrolytes consisting of ethyl magnesium bromide solved in poly(ethylene oxide) have been prepared, containing about one molecule of tetrahydrofuran or dibutylether per magnesium ion. Using these gel-like electrolytes, magnesium ion reduction and reoxidation is demonstrated, and the dependence of conductivity on temperature and composition of the electrolyte system is studied. Best results were obtained with a magnesium content of 5-6 wt.% magnesium, corresponding to an ethylene oxide unit to magnesium ratio of 4:1. At 50 degrees C, these electrolyte systems show conductivities in the range of 10(-5)-10(-4) S cm(-1). Enhanced conductivity is found for systems with a higher content of monomer ether per magnesium.