화학공학소재연구정보센터
Reaction Kinetics and Catalysis Letters, Vol.83, No.2, 337-343, 2004
Palladium-catalyzed isomerization of 1-hexene
The isomerization of 1-hexene over Pd(acac)(2) + BF3OEt2 and Pd(acac)(2) + PPh3 + BF3OEt2 catalyst systems proceeds by the consecutive-parallel scheme. Tetracoordinate square-planar Pd hydrides bearing two vacant coordination sites are likely to be catalytically active species for the isomerization of hexene-1.