Reaction Kinetics and Catalysis Letters, Vol.81, No.2, 357-364, 2004
Chemiluminescence in the reaction of ozone with 1,3-dioxans in aqueous solutions
Chemiluminescence in the visible part of spectrum is found to assist the oxidation of substituted 1,3-dioxans by ozone in aqueous media. The kinetics of the chemiluminescence decay was studied in the temperature interval 323-353 K, and the activation parameters of this process were determined. A kinetic scheme is proposed to explain the results.