Reaction Kinetics and Catalysis Letters, Vol.72, No.1, 147-152, 2001
Oxidation of 1,3-dioxacyclanes with oxone and potassium persulfate catalyzed by 2,2,5,5-tetramethyl-4-phenyl-3-imidazoline-3-oxide-1-oxyl
The catalytic effect of 2,2,5,5-tetramethyl-4-phenyl-3-imidazoline-3-oxide-1-oxyl on the oxidation of 2-isopropyl-1,3-dioxolane. 2-phenyl-1,3-dioxolane, 2-phenyl-4-chlormethy1-1,3-dioxolane, 2-isopropyl-1,3-dioxane, 2-isopropyl-1-methyl-1,3-dioxane, 2-phenyl-1,3-dioxane, 2-phenyl-4-methyl-1,3-dioxane with oxone and potassium persulfate is reported. The corresponding glycol monoesters were obtained with yields of 90-100%.