Macromolecular Rapid Communications, Vol.25, No.15, 1387-1391, 2004
On the beta transition in high density polyethylene: The effect of transcrystallinity
Transcrystallinity in UHMWPE fiber-reinforced HDPE composites promotes a significant beta transition that is untypical of high-density polyethylene. Surface profiling by atomic force microscopy identifies two distinct morphologies in the composite without a boundary phase between them, which coincide with the transcrystalline layer and with the bulk spherulitic matrix. As a result, the claim that attributes this transition to loose chain folds at the lamella surface is favored.
Keywords:atomic force microscopy (AFM);beta relaxation;dielectric properties;polyethylene (PE)/polyethylene composites;transcrystallinity