Facile and effective synthesis of siloxane-based polyamines

Ready TE; Chauhan BPS; Boudjouk P

Macromolecular Rapid Communications, Vol.22, No.8, 654-657, 2001

DOI10.1002/1521-3927(20010501)22:8<654::AID-MARC654>3.0.CO;2-S Export Citation

Facile and effective synthesis of siloxane-based polyamines

Linear and cyclic polysiloxanes with pendant amine moieties have been synthesized via the [(C6H5)(3)P](3)RhCl-catalyzed dehydrogenative alcoholysis of poly(methylhydrosiloxane) (PMHS) or cyclotetra(methylhydrosiloxane) (D4H) with hydroxyalkylamines.