Macromolecular Rapid Communications, Vol.21, No.14, 973-978, 2000
The effect of chain architecture on "sharkskin" of metallocene polyethylenes
Dynamic viscoelastic and extrusion capillary results of metallocene based polyethylenes are analyzed. Three samples show very high viscosities at low frequencies and large relaxation times, which is a symptom of the presence of small amounts of long chain branching (LCB). A linear correlation is found between the sharkskin dynamics (periodicity) and a characteristic entanglement-disentanglement time. It is found that this correlation does not hold for samples suspected of LCB.