Macromolecular Rapid Communications, Vol.17, No.3, 173-180, 1996
(eta(3)-Allyl)palladium(II) catalysts for the addition polymerization of norbornene derivatives with functional groups
Cycloaliphatic polyolefins with functional groups were prepared by the Pd(II)-catalyzed addition polymerization of norbornene derivatives. Homo- and copolymers containing repeating units based on bicyclo[2.2.1]hept-5-en-2-ylmethyl decanoate (endo/exo-ratio = 80/20), bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester (exo/endo = 80/20), bicyclo[2.2.1]hept-5-ene-2-methanol (endo/exo = 80/23), and bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (100% endo) were prepared in 49-99% yields with {(eta(3)-allyl)Pd(BF4)} and [eta(3)-allyl)Pd(SbF6)} as catalysts. The catalyst containing the hexafluoroantimonate ion was slightly more active than the tetrafluoroborate baled Pd-complex.