Macromolecular Rapid Communications, Vol.16, No.2, 125-130, 1995
FOURIER-TRANSFORM INFRARED STUDY OF THE SWITCHING PROCESS IN A FERROELECTRIC LIQUID-CRYSTALLINE POLYMER
The implementation of the step-scan technique on our FT-IR spectrometer enabled us to follow the electric-field induced reorientation dynamics of different molecular segments of a ferroelectric liquid crystalline polymer on a sub-millisecond time scale. It was detected that not only the mesogen but also the spacer and at least part of the backbone take part in the reorientation process.