화학공학소재연구정보센터
Advanced Materials, Vol.13, No.7, 485-485, 2001
The polyrotaxane gel: A topological gel by figure-of-eight cross-links
Supramolecules with topological characteristics have attracted great interest both experimentally and theoretically. A new kind of gel has been obtained by chemically cross-linking polyrotaxane molecules in solution. The polymer chains are topologically interlocked by figure-of-eight cross-links (see Figure), which can pass along the polymer chains freely to equalize the "tension" of the threaded polymer chains just like pulleys. [GRAPHICS]