Applied Surface Science, Vol.253, No.13, 5591-5595, 2007
Modeling of adsorption and phase diagrams for stepped surfaces: Transfer matrix approach
The simplest model of stepped surface has been constructed and scrutinized with different values of model parameters. The transfer matrix method was shown to be a very effective approach. Phase diagrams and local isotherms have been obtained. It was shown that the local coverage can be the non-monotonous function of the total coverage or the chemical potential. (C) 2007 Elsevier B.V. All rights reserved.