Applied Surface Science, Vol.253, No.11, 5040-5044, 2007
Influence of the calcium phosphate content of the target on the phase composition and deposition rate of sputtered films
Calcium phosphate was coated from tetracalcium phosphate (TTCP), hydroxyapatite (HA), beta-tricalcium phosphate (TCP), beta-calcium pyrophosphate (CPP), and beta-calcium metapbosphate (CMP) powder targets using radio frequency magnetron sputtering. The composition of the crystal phase of the coated films was changed, depending on the target materials, and the Ca/P molar ratios of the films varied from 0.74 to 2.54, increasing with the Ca/P molar ratio of the target. The solubility of the target, determined using a microwave-induced plasma-mass spectrometer was: TTCP approximate to beta-CMP > beta-TCP > beta-CPP > HA, and the deposition rate from each target showed a similar order to the solubility: TTCP; CMP > beta-TCP > beta-CPP, HA. (c) 2006 Elsevier B.V. All rights reserved.