The copolymers from different feed ratios of N-(methacryloyloxymethyl) benzotriazole (MMBT) and methyl methacrylate (NIMA) has been synthesised using free radical solution polymerization technique and characterized using FT-IR and (CNMR)-C-13 spectroscopy. The thermal stability of the polymers was studied using theremogravimetrtic analysis (TGA). The corrosion behaviors of mild steel specimens dip coated with different composition of copolymers have been evaluated by potentiodynamic polarization and electrochemical impedance spectroscopic (EIS) method. These electrochemical properties were observed in 0.1 M HCl medium. The polarization and impedance measurements showed different corrosion protection efficiency with change in composition of the copolymers. It was found that the corrosion protection properties are owing to the barrier effect of the polymer layer covered on the mild steel surfaces. However, it Was observed that the copolymer obtained from 1: 1 mole ratio of MMBT and MMA exhibited better protection efficiency than other combinations. (c) 2006 Elsevier B.V. All rights reserved.