ToF-SIMS has been used to analyse tribological induced chemical changes of organic coatings deposited on steel strip hot-dip coated with a 55.0% Al-43.4% Zn-1.6% Si alloy (Aluzink). The organic coating was a styrene-acrylic co-polymer containing different forming additives. The forming properties of the organic coatings were evaluated with modified scratch testing. The friction curves show that organic coated hot-dip coated steel displays significantly better tribological properties, i.e. lower coefficient of friction and lower wear, as compared to hot-dip coated steel. Furthermore, the organic coatings showing the highest material transfer tendency also show the highest wear. ToF-SIMS spectra show that a transfer film consisting of species from the organic coating is formed on the ball counter surface. Finally, a combination of SEM and ToF-SIMS analysis shows that mechanical failure of the coating dominates, i.e. no tribochemical changes of the coatings could be detected in the wear track. (C) 2002 Published by Elsevier Science B.V.