화학공학소재연구정보센터
Journal of Crystal Growth, Vol.229, No.1, 595-600, 2001
Effects of centrifugal acceleration on the flows and segregation in vertical Bridgman crystal growth with steady ampoule rotation
The effects of centrifugal acceleration on the flows and segregation in vertical Bridgman crystal growth with steady ampoule rotation are investigated through numerical simulation. The numerical model is based on the Boussinesq approximation in a rotating frame, and the fluid flow, heat and mass transfer, and the growth interface are solved simultaneously by a robust finite-volume/Newton method. The growth of gallium-doped germanium (GaGe) in the Grenoble furnace is adopted as an example. The calculated results at small Froude number (Fr much less than 1) are consistent with the previous prediction (Lan, J. Crystal growth 197 (1999) 983). However, at a high rotation speed or in reduced gravity, where the centrifugal acceleration becomes important (Fr-l), the results are quite different due to the secondary flow induced. Since the direction of the induced flow is different from that of the buoyancy convection due to the concave interface, the flow damping is more effective than that due to the Coriolis force alone. More importantly, radial segregation can be reversed during the flow transition from one to the other.