화학공학소재연구정보센터
Journal of Crystal Growth, Vol.219, No.3, 300-306, 2000
Evaluation of composition region for peritectic coupled growth
The composition region for stable coupled peritectic growth is evaluated by means of extending Boettinger's analysis. Our present analysis demonstrates that there exists a critical composition between C-alpha (composition of primary a at peritectic equilibrium) and Cp (compostion of peritectic beta at peritectic equilibrium), i.e. C-crit, separating the peritectic plateau (between C-alpha and C-beta) into two regions where coupled and banded growth regimes dominate between C-crit and C-beta and between C-alpha and C-crit, respectively. The calculated critical composition, C-crit, is consistent with the observation in Ni-Al, Ti-Al and Sn-Cd peritectic systems. Effects of interfacial energies of constituent phases and convection on the separation of these two growth regimes are also discussed.