Journal of Crystal Growth, Vol.210, No.1-3, 112-115, 2000
Direct observation of electrically harmful surface defects of Si wafer immersed in slightly Cu-contaminated water
Images of defects generated by immersing silicon wafer in slightly Cu-contaminated water of 500 ppt level were observed for the first time by using a highly sensitive defect detection system and coordinate linked atomic force microscopy. There are three types of surface defects: a protrusion-type defect 100-200 nm wide and 2-10 nm high, a shallow pit 100-200 nm wide and 5-10 nm deep, and a larger shallow pit 1 mu m wide and 2-8 nm deep. They are detected as laser beam scatters with sizes smaller than 90 nm-diam in spherical polystyrene-latex standard particle equivalence. From oxide breakdown characteristics of the wafer, these extremely small or shallow defects are believed to be potential origins which can deteriorate gate oxide integrity.
Keywords:silicon;Cu-contamination;OSDA;AFM;GOI;SC1 repeat-cleaning;protrusion-type defect;shallow pit