The influence of the dopant iodine (I-2) on fluorescence spectra, UV-VIS spectra and photoconductivity of the C-60-toluene derivative is studied. The results show that the photoconductivity of the derivative doped with I-2 has increased by one order of magnitude. The fluorescence and UV-VIS analyses indicate that a charge-transfer complex (CTC) Of C-60-toluene and I-2 may be formed.