Single crystals of buckminsterfullerene (C-60) were grown by low-temperature solution growth technique. Using the same technique, poly(vinylchloride) was doped with ITO of C-60 by mass. FTIR spectra were recorded for pure C-60, pure poly(vinylchloride) and C-60-doped poly(vinylchloride) by Bruker IFS 66V FTIR spectrometer. From the nature of the FTIR spectrum of the C-60-doped material, it is found that the material is polycrystalline and the presence of C-60 has been confirmed. The absorption spectra for C-60 and C-60-doped PVC samples were recorded using SL159 UV-vis spectrophotometer. Photoconductivity studies were also made for these materials. It was interesting to observe that the C-60-PVC exhibited negative photoconductivity. Stockmann model has been successfully applied to explain this behaviour of the doped sample.