Journal of the American Ceramic Society, Vol.89, No.8, 2444-2447, 2006
Particle redistribution during dendritic solidification of particle suspensions
Solidification of the liquid medium in ceramic suspensions containing less than a critical volume fraction powder leads to the formation of particle-free dendrites of the frozen medium. These particle-free dendrites create, after sublimation of the frozen vehicle, large dendrite pores. We define the conditions under which particle-free dendrites form, and relate the size and volume fraction of the dendrites to the volume fraction powder and the solidification rate.