Journal of the American Ceramic Society, Vol.89, No.7, 2167-2171, 2006
Thermal oxidation of aluminum nitride powder
The oxidation kinetics, morphology, and crystallinity of aluminum nitride (AlN) powder thermally oxidized in flowing oxygen were determined from 800 degrees to 1150 degrees C. At 800 degrees C the oxidation became detectable with weight change. AlN powder was almost completely oxidized at 1050 degrees C after only 0.5 h. Amorphous aluminum oxide formed at relatively low temperatures (800 degrees-1000 degrees C), with a linear oxidation rate governed by the oxygen-nitride interfacial reaction. Transmission electron microscopy displayed individual aluminum oxide grains which formed a discontinuous oxide layer at this temperature range. The aluminum oxide was crystalline at higher temperatures (> 1000 degrees C), as detected by X-ray diffraction, and the density of oxide grains increased with temperature.