화학공학소재연구정보센터
Journal of the American Ceramic Society, Vol.87, No.9, 1720-1725, 2004
Process and mechanical properties of in situ silicon carbide-nanowire-reinforced chemical vapor infiltrated silicon carbide/silicon carbide composite
A SiC nanowire/Tyranno-SA fiber-reinforced SiC/SiC composite was fabricated via simple in situ growth of SiC nanowires directly in the fibrous preform before CVI matrix densification; the purpose of the SiC nanowires was to markedly improve strength and toughness. The nanowires consisted of single-crystal P-phase SiC with a uniform similar to5 nm carbon shell; the nanowires had diameters of several tens to one hundred nanometers. The volume fraction of the nanowires in the fabricated composite was similar to5%. However, the composite did not show significant increase in strength and toughness, likely because of strong bonding between the nanowires and the matrix caused by the very thin carbon coating on the nanowires. Little debonding and pullout of SiC nanowires from the matrix were observed at the fracture surfaces of the composite.