Journal of the American Ceramic Society, Vol.87, No.3, 358-364, 2004
Monoclinic zirconia bodies by thermoplastic ceramic extrusion
Two ultrafine, undoped ZrO2 powders with median primary particle sizes of 9 and 25 nm were used to prepare ceramic suspensions for thermoplastic extrusion. The organic vehicle consisted of an industrial-grade poly(ethylene-co-vinyl acetate) (EVA) or polyethylene (PE-HD) and decanoic acid as a dispersing agent. The powder volume loadings achieved were 44% and 52% by volume for the two powders, respectively. The amount of dispersant needed was calculated from a new model based on available chemisorption sites on the powder surface. Mixing and extrusion were conducted using a conventional modular plastic processing unit. Green bodies were dewaxed up to 450degreesC in an inert atmosphere and sintered to full density in air at 1060degrees and 1100degreesC, respectively. Analysis of the ceramic phase content and the microstructure of the bodies is presented.