Gel-glasses of various compositions in the xZrO(2).(10 - x)SiO2 system were fabricated by the sol-gel process. Precipitation due to the different reactivities between tetraethyl orthosilicate (TEOS) and zirconium(IV) n-propoxide has been eliminated through the use of 2-methoxyethanol as a chelating agent. Thermal treatment of these gels produced crystalline ZrO2 particles. While monoclinic is the stable crystalline phase of zirconia at low temperatures, the metastable tetragonal phase is usually the first crystalline phase formed on heat treatment, However, stability of the tetragonal phase is low, and it transforms to the monoclinic phase on further heat treatment. In this study, it has been found that the transformation temperature increases as the SiO2 content in the ZrO2-SiO2 binary oxide increases. The most significant results were from samples containing only 2 mol% SiO2, where the metastable tetragonal phase formed at low temperatures and remained stable over a broad temperature range. X-ray diffraction, transmission electron microscopy, and Fourier transform infrared spectroscopy were used to elucidate the structure of these binary oxides as a function of temperature.