화학공학소재연구정보센터
Journal of Hazardous Materials, Vol.85, No.1-2, 53-72, 2001
Determination of the environmental impact of consolidation induced convective transport through capped sediment
The presence of contaminated sediment poses a barrier to essential waterway maintenance and construction in many ports and harbors, which support 95% of US foreign trade. Cost effective solutions to remediate contaminated sediments in waterways need to be applied. Capping is the least expensive remediation alternative available for marine sediments that is unsuitable for open water disposal. Dredged material capping and in situ capping alternatives, however, are not widely used because regulatory agencies are concerned about the potential for contaminant migration through the caps. Numerous studies have been conducted on the effects of diffusion through caps, however, there is a lack of experimental data documenting the effects of consolidation induced transport of contaminants through caps. This study examines consolidation induced convective contaminant transport in capped sediment utilizing a research centrifuge. In this study, consolidation induced convective transport was modeled for 7 h at 100 x g, which modeled a contaminant migration time of 8 years for a prototype that was 100 times larger than the centrifuge model. In this study, hydrodynamic dispersion was a function of the seepage velocity. And, advection and dispersion dominated the migration of contaminants. Centrifuge model results were compared to an analytical solution for advection and dispersion. The advection-dispersion equation demonstrated that the centrifuge test is a conservative estimate for predicting contaminant transport. In conducting sensitivity analysis of the advection-dispersion equation to the centrifuge modeling, as hydrodynamic dispersion decreased, the time for contaminant breakthrough increased. Moreover, as the sediment to water distribution coefficient increased, the contaminant concentration into the overlying water decreased.