Addition of tetrachloromethane to alkenes catalyzed by copper(I) complexes with N-thioacylamidothiophosphate ligands

Zazybin A; Osipova O; Khusnutdinova U; Aristov I; Solomonov B; Sokolov F; Babashkina M; Zabirov N

Journal of Molecular Catalysis A-Chemical, Vol.253, No.1-2, 234-238, 2006

DOI10.1016/j.molcata.2006.03.033 Export Citation

Addition of tetrachloromethane to alkenes catalyzed by copper(I) complexes with N-thioacylamidothiophosphate ligands

Zazybin A, Osipova O, Khusnutdinova U, Aristov I, Solomonov B, Sokolov F, Babashkina M, Zabirov N

The catalytic activity of copper(I) complexes with N-thioacylamidothiophosphate ligands towards addition reaction of tetrachloromethane to alkenes was investigated. The influence of nucleophilic co-catalysts (alcohols, N-heterocycles, etc.) on catalytic activity of metal complexes was determined. (c) 2006 Elsevier B.V All rights reserved.

Keywords:Kharasch reaction;homogeneous catalysis;copper(I) complexes