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Journal of Molecular Catalysis A-Chemical, Vol.166, No.2, 193-209, 2001
Metal catalysts for the vinyl polymerization of norbornene
A full literature and patent account (about 100 references) is given on work describing the vinyl polymerization to homo-polynorbornene, The interest in vinyl homo-polynorbornene is driven by its dielectric and mechanical properties for the technical application as an interlevel dielectric in microelectronics applications. The norbornene/olefin copolymerization is covered to some extent for comparison. The metal catalysts are presented and important polymer product properties are emphasized.