Direct synthesis of the novel 2-D mixed-ligands lead(II) complex, crystal structure of [Pb(4,4'-bpy)(NO3)(SCN)](n) (4,4'-bpy=4,4'-bipyridine): (A new polymeric compound with three bridged ligand and inactive lone pair)

Morsali A; Mahjoub AR

Chemistry Letters, Vol.33, No.1, 64-65, 2004

DOI10.1246/cl.2004.64 Export Citation

Direct synthesis of the novel 2-D mixed-ligands lead(II) complex, crystal structure of [Pb(4,4'-bpy)(NO3)(SCN)](n) (4,4'-bpy=4,4'-bipyridine): (A new polymeric compound with three bridged ligand and inactive lone pair)

Morsali A, Mahjoub AR

A lead(II) complex with three ligands, 4,4'-bipyridine (4,4'bpy), nitrate, and thiocyanate, has been synthesized and characterized by CHN elemental analysis, IR-, H-1-, C-13- and Pb-207 NMR spectroscopy. The single-crystal X-ray data of [Pb(4,4'-bpy)(NO3)(SCN)](n), compound shows that the complex to be two dimensional polymeric and the Pb atom has an eight-coordinate geometry. The lone pair of electrons on lead(II) is inactive in this complex.