Chemistry Letters, Vol.29, No.11, 1302-1303, 2000
Stereocontrolled synthesis of a tetracyclic sesterterpene, (+)-scalarenedial
A stereocontrolled, formal synthesis of a tetracyclic sesterterpene, (+)-scalarenedial, was achieved by means of repeating the same ring construction method and a simple resolution of the intermediary tetracyclic beta -ketoester with a chiral auxiliary.