Journal of Power Sources, Vol.167, No.1, 58-63, 2007
Enhanced performance of a single-chamber solid oxide fuel cell with an SDC-impregnated cathode
The electrochemical performance of anode-supported single-chamber solid oxide fuel cells (SC-SOFCs) with and without SDC-impregnated cathodes was compared in a diluted methane-oxygen mixture. These cells were made of conventional materials including yttrium-stabilized zirconia (YSZ) thin film, a Ni + YSZ anode and a La0.7Sr0.3MnO3 (LSM) cathode. Our results showed that the cell performance was greatly enhanced with the SDC-impregnated LSM cathode. At a furnace temperature of 750 degrees C, the maximum power density was as high as 404 mW cm(-2) for a CH4 to O-2 ratio of 2:1, which was 4.0 times higher than the cell with a pure LSM cathode (100 mW cm(-2)). The overall polarization resistance of the impregnated cell was 1.6 ohm cm(2), which was much smaller than that of the non-impregnated one (4.2 ohm cm2). The impregnation introduced SDC nanoparticles greatly extended the electrochemical active zone and hence greatly improved the cell performance. (C) 2007 Elsevier B.V. All rights reserved.
Keywords:single-chamber solid oxide fuel cells;anode-supported;ion impregnation;La0.7Sr0.3MnO3;electrochemical performance