Ba0.9Sr0.1TiO3 powder was processed at 80 degrees C by reacting Ti sol in aqueous solutions that contained BaCl2, SrCl2 and NaOH at atmospheric pressure. Well-crystallized, spherical, nanosizes powders were formed by this method. The powders were found to have a cubic structure, which was retained even after heating at 900 degrees C. Sintering at 1400 degrees C, led to the formation of a tetragonal structure with a secondary phase of Ba6Ti17O40. Abrupt grain growth was observed at 1400 degrees C. The electrical response of the sample sintered at 1400 degrees C has three electrically different regions. Each region of the sample is represented by different RC element. Element 1 (R (1) C (1)) is the most resistive and its capacitance ishigh (0.5 nFcm(-1)) indicating a thin region, probably the grain boundary. Element 2 (R (2) C (2)) shows a smaller resistance value compared to element 1. The capacitance value of element 2 is temperature-dependent and displays a Curie-Weiss behaviour, indicative of a ferroelectric material above T (c). The lower capacitance of C (2) (15 pFcm(-1)) indicates that it is a much thicker region than element 1 and can be assigned as a ferroelectric bulk region. Element 3 is probably an electrode effect.